Disc 1:
1) Heartbreaker - will.i.am & Cheryl Cole ()
2) If I Never See Your Face Again - Maroon 5 & Rihanna ()
3) Broken Strings - James Morrison & Nelly Furtado ()
4) Rise and Fall - Craig David & Sting ()
5) If You Ever - East 17 & Gabrielle ()
6) Shine a Light - McFly & Taio Cruz ()
7) Supernova - Mr Hudson & Kanye West ()
8) Dilemma - Nelly & Kelly Rowland ()
9) Promiscuous - Nelly Furtado & Timerland ()
10) She's Like a Star - Sugababes & Taio Cruz ()
11) How Deep Is Your Love - Dru Hill & Redman ()
12) Let Me Blow Your Mind - Eve & Gwen Stefani ()
13) Breathe (Feat. Sean Paul) - Blu Cantrell ()
14) Could It Be I'm Falling in Love - David Grant & Jaki Graham ()
15) It's Too Late - Dina Carroll & Quartz ()
16) Father and Son - Ronan Keating & Yusuf ()
17) I'll Be Your Baby Tonight - Robert Palmer & UB40 ()
18) Mama Told Me Not to Come - Tom Jones & Stereophonics ()
19) This Is Not America - Claudia Brucken & Paul Rutherford ()
20) What Becomes of the Broken Hearted - Dave Stewart & Colin Blunstone ()
Disc 2:
1) Endless Love - Lionel Richie & Diana Ross ()
2) Up Where We Belong - Joe Cocker & Jennifer Warnes ()
3) Baby, Come to Me - Patti Austin & James Austin ()
4) We've Got Tonight - Kenny Rogers & Sheena Easton ()
5) With You I'm Born Again - Billy Preston & Syreeta ()
6) Delicate - Terence Trent D'Arby & Desree ()
7) You Are Everything - Diana Ross & Marvin Gaye ()
8) You're All I Need to Get By - Marvin Gaye & Tammi Terrell ()
9) Tonight I Celebrate My Love - Peabo Bryson & Roberta Flack ()
10) Senza Una Donna (Without a Woman) - Zucchero & Paul Young ()
11) Something's Gotten Hold of My Heart - Marc Almond & Gene Pitney ()
12) I'm Gonna Make You Love Me - Diana Ross & The Supremes & The Temptations ()
13) Left of Center - Suzanne Vega & Joe Jackson ()
14) I Wanna Stay With You - Gallagher & Lyle ()
15) It's My Party - Dave Stewart & Barbara Gaskin ()
16) The Ballad of Tom Jones - Space & Cerys Matthews ()
17) I'll Find My Way Home - Jon & Vangelis ()
18) Blue Guitar - Justin Hayward & John Lodge ()
19) Haunted - Shane McGowan & The Popes & Sinead O'Connor ()
20) Stop, Look, Listen to Your Heart - Diana Ross & Marvin Gaye ()
Disc 3:
1) It Takes Two - Marvin Gaye & Kim Weston ()
2) Too Much, Too Little, Too Late - Johnny Mathis & Deniece Williams ()
3) Ain't Nothing Like the Real Thing - Marvin Gaye & Tammi Terrell ()
4) We Do It - R&J Stone ()
5) Solid - Ashford & Simpson ()
6) I Got You Babe - Sonny & Cher ()
7) Reunited - Peaches & Herb ()
8) Teardrops - Womack & Womack ()
9) Think It Over - Cissy Houston & Whitney Houston ()
10) The Girl from Ipanema - Astrud Gilbero & Stan Getz ()
11) The Times They Are A-changin' - Barbara Dickson & Gerry Rafferty ()
12) Early in the Morning - John Mayall & Chris Rea ()
13) Hey Paula! - Paul & Paula ()
14) Dream a Little Dream of Me - Louis Armstrong & Ella Fitzgerald ()
15) Sweet Insomnia - Gwyn & Will ()
16) Summer Nights - John Barrowman & Shona Lindsay ()
17) I Know Him So Well - Barbara Dickson & Elaine Paige ()
18) Amigos Para Siempre (Friends for Life) - Sarah Brightman & Jose Carreras ()
19) The Phantom of the Opera - Dave Willetts & Lesley Garrett ()
20) All I Ask of You - Michael Crawford & Barbara Bonney ()